{"id":11,"date":"2021-08-16T14:41:00","date_gmt":"2021-08-16T05:41:00","guid":{"rendered":"https:\/\/www-p.sci.ocha.ac.jp\/kuwabara-group-test\/?page_id=11"},"modified":"2025-07-28T16:24:44","modified_gmt":"2025-07-28T07:24:44","slug":"publications","status":"publish","type":"page","link":"https:\/\/www-p.sci.ocha.ac.jp\/kuwabara-group\/publications\/","title":{"rendered":"Publications"},"content":{"rendered":"

Original Papers<\/h2>\n

<2025><\/h4>\n

42. Effects of Countercations in Dianionic Dibenzosilepinyl Salts on the Structure and Hyperconjugative Antiaromaticity<\/p>\n

Kana Kobayashi, Takuya Kuwabara*<\/p>\n

Organometallics<\/em>\u00a02025<\/strong>, 44<\/em>, 1483-1490.<\/p>\n

DOI: 10.1021\/acs.organomet.5c00149<\/a><\/p>\n

41. Gram-scale Synthesis of Dibenzo[a<\/em>,e<\/em>]pentalenes from Trialkyl(phenylethynyl)silanes via Organosodium Intermediates<\/p>\n

Ayane Sato, Takuya Kuwabara*<\/p>\n

J. Org. Chem.<\/em> 2025<\/strong>, 90<\/em>, 9258-9262.<\/p>\n

DOI: 10.1021\/acs.joc.5c00458<\/a><\/p>\n

Preprint ver.: ChemRxiv<\/em>. 2025<\/strong><\/p>\n

DOI: 10.26434\/chemrxiv-2025-8dmvw-v2<\/p>\n

40. Synthesis of a dilithiobutadiene bearing extremely bulky silyl substituents and its reactivity toward functionalized silanes<\/p>\n

Katharina Munster, Shunsuke Kudo, Takuya Kuwabara, Eriko Shimamura, Shunsuke Furukawa, Yusuke Yoshida, Shintaro Ishida, Takeaki Iwamoto, Kazuki Tanifuji, Yasuhiro Ohki, Mao Minoura, Masaichi Saito*<\/p>\n

Dalton Trans<\/em>. 2025<\/strong>, 54<\/em>, 4030-4038.<\/p>\n

DOI: 10.1039\/D4DT03537B<\/a><\/p>\n

<2024><\/h4>\n

39. 5,10-Diiododibenzo[a,e]pentalene<\/p>\n

Natsumi Ohara, Chinatsu Ogiwara, Takuya Kuwabara*<\/p>\n

Molbank<\/em> 2024<\/strong>, 2024<\/em>, M1937.<\/p>\n

DOI: 10.3390\/M1937<\/a><\/p>\n

38. 9,10-Bis(5H<\/em>-dibenzo[b<\/em>,f<\/em>]azepino)anthracene<\/p>\n

Himeko Kawaguchi, Takuya Kuwabara<\/p>\n

Molbank<\/em> 2024<\/strong>, 2024<\/em>, M1917.<\/p>\n

DOI: 10.3390\/M1917<\/a><\/p>\n

 <\/p>\n

37. Arylboronic Acid Pinacol Esters as Stable Boron Sources for
\nDihydrodibenzoborepin Derivatives and a Dibenzoborole<\/p>\n

Himeko Kawaguchi, Kotomi Fuse, Nanoka Maeda, Takuya Kuwabara<\/p>\n

Molecules<\/em> 2024<\/strong>, 29<\/em>, 4024.<\/p>\n

DOI: 10.3390\/molecules29174024<\/a><\/p>\n

preprint ver.: Preprints<\/em> 2024<\/strong>, 2024071789. (DOI: 10.20944\/preprints202407.1789.v1<\/a>)<\/p>\n

\"\"<\/p>\n

36. Lithium Salt of 2,5-Bis(trimethylsilyl)stannolyl Anion: Synthesis, Structure, and Nonaromatic Character<\/p>\n

Kohei Kitamura, Youichi Ishii, Takuya Kuwabara<\/p>\n

Inorganics<\/em> 2024<\/strong>, 12<\/em>, 92.<\/p>\n

DOI: 10.3390\/inorganics12030092<\/a><\/p>\n

\"\"<\/p>\n

<2023><\/h4>\n

35. Retro-Vinylidene Rearrangements of P- and S-Substituted Ruthenium Vinylidene Complexes
\nTakahiro Iwamoto, Kyoka Saito, Takuya Mitsubo, Takuya Kuwabara, Youichi Ishii
\nOrganometallics<\/em> 2023<\/strong>, 42<\/em>, 167\u2013173.
\nDOI: 10.1021\/acs.organomet.2c00552<\/a><\/p>\n

\"\"<\/p>\n

34.\u00a0Exo-<\/em>\u00a0and\u00a0endo<\/em>-Isomers of Plumbylenes Supported by 1,3-Diethers of Calix[4]arene<\/p>\n

Ryunosuke Kuriki, Youichi Ishii, Takuya Kuwabara*<\/p>\n

Eur. J. Inorg. Chem.<\/em>\u00a02023<\/strong>,\u00a026<\/em>, e202200655.<\/p>\n

Selected as EurJIC Talents<\/em><\/p>\n

DOI:\u00a010.1002\/ejic.202200655<\/a><\/p>\n

\"\"<\/p>\n

<2022><\/h4>\n

33. Inorganic salt-assisted assembly of anionic \u03c0-conjugated rings enabling 7<\/sup>Li NMR-based evaluation of antiaromaticity<\/p>\n

Shotaro Ito, Youichi Ishii, Takuya Kuwabara*<\/p>\n

Dalton Trans.<\/em> 2022<\/strong>, 51<\/em>, 16397\u201316402.<\/p>\n

DOI: 10.1039\/D2DT02649J<\/a><\/p>\n

\"\"<\/p>\n

32. Perfluorocycloparaphenylenes<\/p>\n

Hiroki Shudo, Motonobu Kuwayama, Masafumi Shimasaki, Taishi Nishihara, Youhei Takeda, Takuya Kuwabara, Akiko Yagi, Yasutomo Segawa,* Kenichiro Itami*<\/p>\n

Nat. Commun.<\/em> 2022<\/strong>, 13<\/em>, 3713.<\/p>\n

DOI: 10.1038\/s41467-022-31530-x<\/a><\/p>\n

PrePrint version: DOI: 10.33774\/chemrxiv-2021-7kd63<\/a><\/p>\n

\"\"<\/p>\n

31. Weakly Bound Dimer of a Diaryloxygermylene Derived from a
\nt<\/sup><\/em>BuPh2<\/sub>Si-Substituted 2,2′-Methylenediphenol<\/p>\n

Ryo Yamazaki, Ryunosuke Kuriki, Asuka Sugihara, Youichi Ishii and Takuya Kuwabara*<\/p>\n

Crystals<\/em> 2022<\/strong>, 12<\/em>, 605.<\/p>\n

DOI: 10.3390\/cryst12050605<\/a><\/p>\n

\"\"<\/p>\n

30. Experimental Observation of \u03b2-Carbon Elimination from Alkenylrhodium Complexes through Exchange Reactions of the Alkenyl Unit<\/p>\n

Takahiro Iwamoto, Koushi Shibuya, Tomoyuki Takakuwa, Takuya Kuwabara, Youichi Ishii*<\/p>\n

Organometallics<\/em> 2022<\/strong>, 41, 182\u2013186.<\/p>\n

DOI: 10.1021\/acs.organomet.1c00695<\/a><\/p>\n

\"\"<\/p>\n

<2021><\/h4>\n

29. A new strategy for hyperconjugative antiaromatic compounds utilizing negative charges: a dibenzo[b<\/em>,f<\/em>]silepinyl dianion<\/p>\n

Shotaro Ito, Youichi Ishii, Kazuya Ishimura, Takuya Kuwabara*<\/p>\n

Chem. Commun.<\/em> 2021<\/strong>, 57<\/em>, 11330\u201311333.<\/p>\n

DOI: 10.1039\/D1CC04434F<\/a><\/p>\n

\"\"<\/p>\n

<2020><\/h4>\n

28. Selective Double CH Activation at a Methylene Carbon in Methylenediphenol Derivatives to Generate Carbene-Bridged Dinuclear Iridium Complexes<\/p>\n

Takuya Kuwabara, Takuya Toriumi, Mika Suzuki, and Youichi Ishii*<\/p>\n

Organometallics<\/em> 2020<\/strong>, 39<\/em>, 4500\u20134509.<\/p>\n

DOI:10.1021\/acs.organomet.0c00595<\/a><\/p>\n

\"\"\"\"<\/p>\n

Selected as the cover picture of issue 24.<\/p>\n

27. Synthesis and Structures of Diaryloxystannylenes and -plumbylenes embedded in 1,3-Diethers of Thiacalix[4]arene<\/p>\n

Ryunosuke Kuriki, Takuya Kuwabara,* and Youichi Ishii*<\/p>\n

Dalton Trans<\/em>. 2020<\/strong>, 49<\/em>, 12234\u201312241.<\/p>\n

DOI:10.1039\/D0DT02496A<\/a><\/p>\n

\"\"<\/p>\n

26. A Tin Analogue of the Cycloheptatrienyl Anion: Synthesis, Structure, and Further Reduction to Form a Dianionic Species<\/p>\n

Shotaro Ito, Takuya Kuwabara,* and Youichi Ishii*<\/p>\n

Organometallics<\/em> 2020<\/strong>, 39<\/em>, 640\u2013644.<\/p>\n

DOI:10.1021\/acs.organomet.0c00042<\/a><\/p>\n

\"\"<\/p>\n

25. Ruthenium Vinylidene Complexes Generated by Selective 1,2-Migration of P- and S- Substituents: Synthesis, Structures, and Dichromism Arising from an Intermolecular CH\u2026O Hydrogen Bond<\/p>\n

Takuya Kuwabara, Yutaka Aoki, Kousuke Sakajiri, Kazuki Deguchi, ShuheiTakamori, Ai Hamano, Keiko Takano, Hirohiko Houjou and Youichi Ishii*<\/p>\n

Organometallics<\/em> 2020<\/strong>, 39<\/em>, 711\u2013718.<\/p>\n

DOI:10.1021\/acs.organomet.9b00856<\/a><\/p>\n

<2019><\/h4>\n

24. Inverted Sandwich Rh Complex Bearing a Plumbole Ligand and Its Catalytic Activity<\/p>\n

Masaichi Saito, Marisa Nakada, Takuya Kuwabara, Ryota Owada, Shunsuke Furukawa, Radhika Narayanan, Ninori Abe, Masahiko Hada, Ken Tanaka, Yoshihiko Yamamoto<\/p>\n

Organometallics<\/em> 2019<\/strong>, 38<\/em>, 3099\u20133103.<\/p>\n

DOI:10.1021\/acs.organomet.9b00339<\/a><\/p>\n

23. Synthesis of Phosphaphenalenium Salts via P\u2013C Reductive Elimination at a Ru(II) Center and Their Fluorescence Properties<\/p>\n

Takahiro Kato, Takuya Kuwabara, Yasunori Minami, Tamejiro Hiyama, and Youichi Ishii*<\/p>\n

Bull. Chem. Soc. Jpn.<\/em> 2019<\/strong>, 92<\/em>, 1131\u20131141.<\/p>\n

DOI:10.1246\/bcsj.20190090<\/a><\/p>\n

22. Molybdenum-Mediated Vinylidene Rearrangement of Internal Acylalkynes and Sulfonylalkynes<\/p>\n

Takuya Kuwabara, Kousuke Sakajiri, Yousuke Oyama, Shintaro Kodama , and Youichi Ishii*<\/p>\n

Organometallics<\/em> 2019<\/strong>, 38<\/em>, 1560\u20131566.<\/p>\n

DOI:10.1021\/acs.organomet.9b00019<\/a><\/p>\n

<2018><\/h4>\n

21. Ring Slippage and Dissociation of Pentamethylcyclopentadienyl Ligand in an (\u03b75<\/sup>-Cp*)Ir Complex with a \u03ba3<\/sup>–O<\/em>,C<\/em>,O<\/em> Tridentate Calix[4]arene Ligand under Mild Conditions<\/p>\n

Takuya Kuwabara, Ryogen Tezuka, Mikiya Ishikawa, Takuya Yamazaki, Shintaro Kodama and Youichi Ishii*<\/p>\n

Organometallics<\/em> 2018<\/strong>, 37<\/em>, 1829\u20131832.<\/p>\n

DOI:10.1021\/acs.organomet.8b00257<\/a><\/p>\n

20. Dinuclear Nickel Complexes Doubly Bridged by Hydrogencyanamido Ligands: Synthesis, Structures and Magnetic Properties<\/p>\n

Takuya Kuwabara, Natsumi Shiga, Shintaro Kodama, Hirohiko Sato, Hirohiko Houjou and Youichi Ishii*<\/p>\n

Eur. J. Inorg. Chem.<\/em> 2018<\/strong>, 3413\u20133417.<\/p>\n

DOI:10.1002\/ejic.201800457<\/a><\/p>\n

19. P\u2013C reductive elimination in Ru(II) complexes to convert triarylphosphine ligands into five- or six-membered phosphacycles<\/p>\n

Takuya Kuwabara, Takahiro Kato, Kouichi Takano, Shintaro Kodama, Yuuka Manabe, Noriko Tsuchida, Keiko Takano, Yasunori Minami, Tamejiro Hiyama and Youichi Ishii*<\/p>\n

Chem. Commun.<\/em> 2018<\/strong>, 54<\/em>, 5357\u20135360.<\/p>\n

DOI:10.1039\/C8CC02539H<\/a><\/p>\n

18. Activation of a Carbon-Carbon Bond in Internal Alkynes: Vinylidene Rearrangement of Disubstituted Alkynes at an Ir Complex<\/p>\n

Takuya Kuwabara, Shuhei Takamori, Satoshi Kishi, Takahiro Watanabe, Yousuke Ikeda, Shintaro Kodama, Yasunori Minami, Tamejiro Hiyama, Youichi Ishii*<\/p>\n

Synlett<\/em>\u00a02018<\/strong>, 29<\/em>, 727\u2013730.<\/p>\n

DOI:10.1055\/s-0036-1591511<\/a><\/p>\n

<2017><\/h4>\n

17. Reactions of Dilithium Dibenzopentalenides with Cr(CO)3<\/sub>(CH3<\/sub>CN)3<\/sub>: Unexpected Formation of A Cubic Tetramer of An Anionic Hydrodibenzopentalenyl Complex<\/p>\n

Takuya Kuwabara, Nobuaki Kurokawa, Masaichi Saito*<\/p>\n

ChemPlusChem<\/em> 2017<\/strong>, 82<\/em>, 1039\u20131042.<\/p>\n

DOI:org\/10.1002\/cplu.201700043<\/a><\/p>\n

16. Synthesis and reactivity of a ruthenocene-type complex bearing an aromatic \u03c0-ligand with the heaviest group 14 element<\/p>\n

Marisa Nakada, Takuya Kuwabara, Shunsuke Furukawa, Masahiko Hada, Mao Minoura, Masaichi Saito<\/p>\n

Chem. Sci.<\/em> 2017<\/strong>, 8<\/em>, 3092\u20133097.<\/p>\n

DOI:10.1039\/C6SC04843A<\/a><\/p>\n

<2016><\/h4>\n

15. (\u03b74<\/sup>-Butadiene)Sn(0) Complexes: A New Approach for Zero-valent p-Block Elements Utilizing a Butadiene as a 4\u03c0-Electron Donor<\/p>\n

Takuya Kuwabara, Marisa Nakada, Jumpei Hamada, Jing-dong Guo, Shigeru Nagase, Masaichi Saito<\/p>\n

J. Am. Chem. Soc<\/em>. 2016<\/strong>, 138<\/em>, 11378\u201311382.<\/p>\n

DOI:10.1021\/jacs.6b07304<\/a><\/p>\n

Highlighted in Chemistry Views<\/a>\u3001\u57fc\u7389\u5927\u5b66\u30d7\u30ec\u30b9\u30ea\u30ea\u30fc\u30b9<\/p>\n

<2015><\/h4>\n

14. Synthesis of a Stannole Dianion Complex Bearing a \u03bc-\u03b71<\/sup>;\u03b71<\/sup>-Coordination Mode: Different Electronic State of Stannole Dianion Ligands Depending on Their Hapticity<\/p>\n

Takuya Kuwabara, Masaichi Saito<\/p>\n

Organometallics<\/em> 2015<\/strong>, 34<\/em>, 4202\u20134204.<\/p>\n

DOI:10.1021\/acs.organomet.5b00614<\/a><\/p>\n

13. Diverse Coordination Modes in Tin Analogues of Cyclopentadienyl Anion Depending on the Substituents on the Tin Atom<\/p>\n

Takuya Kuwabara, Marisa Nakada, Jing-Dong Guo, Shigeru Nagase, Masaichi Saito<\/p>\n

Dalton Trans<\/em>. 2015<\/strong>, 44<\/em>, 16266\u201316271.<\/p>\n

DOI:10.1039\/C5DT02202A<\/a><\/p>\n

Selected as the front inside cover\u3001Highlighted in A News Paper (\u65e5\u520a\u5de5\u696d\u65b0\u805e)\u3001
\nChem-Station \u7b2c 4 \u56de\u30b9\u30dd\u30c3\u30c8\u30e9\u30a4\u30c8\u30ea\u30b5\u30fc\u30c1<\/a>\u3001\u57fc\u7389\u5927\u5b66\u30d7\u30ec\u30b9\u30ea\u30ea\u30fc\u30b9<\/p>\n

12. Curved Oligophenylenes as Donors in Shape-Persistent Donor-Acceptor Macrocycles with Solvatofluorochromic Properties<\/p>\n

Takuya Kuwabara, Jun Orii, Yasutomo Segawa, Kenichiro Itami<\/p>\n

Angew. Chem. Int. Ed.<\/em> 2015<\/strong>, 54<\/em>, 9646\u20139649.<\/p>\n

DOI:10.1002\/anie.201503397<\/a><\/p>\n

Highlighted in ACS Central Science (DOI: 10.1021\/acscentsci.5b00339<\/a>)<\/p>\n

11. Palladium-free Synthesis of [10]Cycloparaphenylene<\/p>\n

Yasutomo Segawa, Takuya Kuwabara, Katsuma Matsui, Satoru Kawai, Kenichiro Itami<\/p>\n

Tetrahedron<\/em>\u00a02015<\/strong>, 26\u201327<\/em>, 4500\u20134503.<\/p>\n

DOI:10.1016\/j.tet.2015.02.066<\/a><\/p>\n

10. A Reversible Two-electron Redox System Involving a Divalent Lead Species<\/p>\n

Masaichi Saito, Marisa Nakada, Takuya Kuwabara, Mao Minoura<\/p>\n

Chem. Commun.<\/em> 2015<\/strong>, 51<\/em>, 4674\u20134676.<\/p>\n

DOI:10.1039\/C4CC09856K<\/a><\/p>\n

<2014><\/h4>\n

9. Synthesis, Structures and Electronic Properties of Triple- and Double-Decker Ruthenocenes Incorporated by A Metallole Dianion Ligand<\/p>\n

Takuya Kuwabara, Jing-Dong Guo, Shigeru Nagase, Takahiro Sasamori, Norihiro Tokitoh, Masaichi Saito<\/p>\n

J. Am. Chem. Soc.<\/em> 2014<\/strong>, 136<\/em>, 13059\u201313064.<\/p>\n

DOI:10.1021\/ja507330p<\/a><\/p>\n

\u57fc\u7389\u5927\u5b66\u30d7\u30ec\u30b9\u30ea\u30ea\u30fc\u30b9<\/p>\n

8. Enhancement of Stannylene Character in Stannole Dianion Equivalents Evidenced by NMR, M\u00f6ssbauer Spectroscopies and Theoretical Studies of Newly Synthesized Silyl-substituted Dilithiostannoles<\/p>\n

Takuya Kuwabara, Jing-Dong Guo, Shigeru Nagase, Mao Minoura, Rolfe H. Herber, Masaichi Saito<\/p>\n

Organometallics<\/em> 2014<\/strong>, 33<\/em>, 2910\u20132913.<\/p>\n

DOI:10.1021\/om5003717<\/a><\/p>\n

7. Facile Synthesis of Dibenzopentalene Dianions and Their Application as New \u03c0- extended Ligands<\/p>\n

Takuya Kuwabara, Kazuya Ishimura, Takahiro Sasamori, Norihiro Tokitoh, Masaichi Saito<\/p>\n

Chem. Eur. J.<\/em> 2014<\/strong>, 20<\/em>, 7571\u20137575.<\/p>\n

DOI:10.1002\/chem.201402304<\/a><\/p>\n

6. Diversity of the Structures in a Distannene Complex and its Reduction to Generate Six-membered Ti2<\/sub>Sn4<\/sub> Ring Complex<\/p>\n

Takuya Kuwabara, Jing-Dong Guo, Shigeru Nagase, Masaichi Saito<\/p>\n

Angew. Chem. Int. Ed.<\/em> 2014<\/strong>, 53<\/em>, 434\u2013438.<\/p>\n

DOI:10.1002\/anie.201308565<\/a><\/p>\n

<2013><\/h4>\n

6. Unexpected Formation of Ru2<\/sub>Sn2<\/sub> Bicyclic Four-Membered Ring Complexes with Butterfly and Inverse-Sandwich Structures<\/p>\n

Takuya Kuwabara, Masaichi Saito, Jing-Dong Guo, Shigeru Nagase<\/p>\n

Inorg. Chem.<\/em> 2013<\/strong>, 52<\/em>, 3585\u20133587.<\/p>\n

DOI:10.1021\/ic302782n<\/a><\/p>\n

<2011><\/h4>\n

4. Synthesis of a Novel Lithocene that has Aromatic-like Nature with Non-aromatic Rings<\/p>\n

Masaichi Saito, Takuya Kuwabara, Kazuya Ishimura, Shigeru Nagase<\/p>\n

Chem. Asian. J.<\/em> 2011<\/strong>, 6<\/em>, 2907\u20132910.<\/p>\n

DOI:10.1002\/asia.201100619<\/a><\/p>\n

3. 1,1′-Di-tert-butyl-2,2′,3,3′,4,4′,5,5′-octaethyl-1,1′-bistannole<\/p>\n

Takuya Kuwabara, Masaichi Saito<\/p>\n

Acta Cryst.<\/em> 2011<\/strong>, E67<\/em>, m949.<\/p>\n

DOI10.1107\/S1600536811022951<\/a><\/p>\n

<2010><\/h4>\n

2. Synthesis, Structure and Reaction of Tetraethyldilithiostannole<\/p>\n

Masaichi Saito, Takuya Kuwabara, Chika Kambayashi, Michikazu Yoshioka, Kazuya Ishimura, Shigeru Nagase<\/p>\n

Chem. Lett.<\/em> 2010<\/strong>, 39<\/em>, 700\u2013701.<\/p>\n

DOI: 10.1246\/cl.2010.700<\/a><\/p>\n

Selected as Editor\u2019s Choice<\/p>\n

1. Synthesis and Structures of Lithium Salts of Stannole Anions<\/p>\n

Masaichi Saito, Takuya Kuwabara, Kazuya Ishimura, Shigeru Nagase<\/p>\n

Bull. Chem. Soc. Jpn.<\/em> 2010<\/strong>, 83<\/em>, 825\u2013827.<\/p>\n

DOI: 10.1246\/bcsj.20100057<\/a><\/p>\n

Books and Reviews<\/h2>\n

1. Review de Debut “\u74b0\u3072\u305a\u307f\u3092\u3082\u3064\u4e09\u914d\u4f4d\u30ea\u30f3\u5316\u5408\u7269\u306e\u89e6\u5a92\u958b\u767a”<\/p>\n

\u6709\u6a5f\u5408\u6210\u5316\u5b66\u5354\u4f1a\u8a8c, 2018, 76, 1100\u20131101.<\/p>\n

DOI: org\/10.5059\/yukigoseikyokaishi.76.1100<\/a><\/p>\n

2. Siloles, Germoles, Stannoles, and Plumboles<\/p>\n

Takuya Kuwabara, Masaichi Saito<\/p>\n

Comprehensive Heterocyclic Chemistry IV (Fourth Edition)<\/em><\/p>\n

2022<\/strong>, 3<\/em>, 798\u2013832.<\/p>\n

DOI: 10.1016\/B978-0-12-409547-2.14789-4<\/a><\/p>\n

<\/div>\n
<\/div>\n","protected":false},"excerpt":{"rendered":"

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